Experimental Result of The Latent Heat Storage Prototype Designed For the Electro-Solar Hybrid Station (SEGS)

 

 
 
 
 

 

 

 

File partitions

 

 

1-Introduction

 

 

2-OPERATION WAY OF LATENT THERMAL TANK PATTERN

 

 

3-EXPERIMENTAL RESULTS FOR THE LATENT THERMAL STORAGE TANK PROTOTYPE

 

 

4-CONCLUSIONS

 

 

5-REFERENCES

 

Experimental Result of The Latent Heat Storage Prototype Designed For the Electro-Solar Hybrid Station (SEGS)
النتائج التجريبية لنموذج الحراري الكامن المُصمم للمحطة الكهروشمسية الهجينة (SEGS)
الناشر : جامعة دمشق
 
 
  Dr.E.Mohamed Riad Jassem
   د.م. محمد رياض جاسم
 
   
 

Abstract

 

The experimental and design work of the developed thermal storage tank is revealed by the geometric form of the designed thermal storage pattern, and presentation of design methodology of this pattern, through existence of thermal isolator of (mineral wool) on the long of nitrates salts Tank, this stored energy is used for covering the different loads at increasing of normal solar radiation intensity in electro-solar station during the day. And designing modeling of the solar power station through the (TRNSYS) program, in addition to preparing an integrated program to study the indicators of the complete thermal storage tank system at startup during the day. In this research, we concentrated on the study of the experimental  results of the  Latent Heat Storage tank which uses a mixture of  phase  change materials( PCM:phase change material), the selected (PCM) in this research is a mixture of sodium nitrates salt and potassium nitrates salt  (NaNO3: KNO3) in ratio (60:40%), where we tested this salty mixture using the developed special apparatus device called  (Differential Scanning Calorimetry ,DSC) for recognition the physical and chemical  specifications  of the salty mixture , it became clear  that  the melting temperature of this mixture is (228.521°C) and the latent heat of phase change from solid to liquid is for the molten salts(114.321 KJ/Kg),the results were identical for the temperature and latent heat according to many of the references in addition that the heat storage tank pattern possesses energy efficiency reaches to percentage (0.96) while the other types of thermal tanks working on (PCM) reach to thermal energy efficiency (0.66-0.70),consequently, the heat storage tank has high latent energy suitable for the work of  electro-solar stations  during different  period  in a day.                                            

 

   
  Keywords: Thermal storage, solar radiation latent heat, hybrid stations, phase change materials (PCM), nitrates salts, thermal efficiency
   
 

الملخص


تم الكشف عن العمل التجريبي والتصميمي لخزان التخزين الحراري المُطور من خلال الشكل الهندسي لنموذج الخزان الحراري المُصمم ، وعرض منهجية تصميم هذا النموذج من خلال وجود عازل حراري (الصوف المعدني) على امتداد خزان لأملاح النترات حيث يتم استخدام هذه الطاقة المخزنة لتغطية الأحمال الحرارية المختلفة عند ازدياد كثافة الإشعاع الشمسي الناظمي في محطة الطاقة االكهروشمسية خلال النهار وتصميم نمذجة المحطة الكهروشمسية عن طريق برنامج( TRNSYS) بالإضافة لإعداد برنامج متكامل لدراسة مؤشرات نظام خزان التخزين الحراري عند بدء التشغيل خلال اليوم. في هذا البحث ركزنا على دراسة النتائج التجريبية لخزان التخزين الحراري الكامن الذي يستخدم مزيجًا من مواد متغيرة الطور  (PCM: مادة متغيرة الطور) والمختارة في هذا البحث عبارة عن خليط من ملح نترات الصوديوم وملح نترات البوتاسيوم (NaNO3: KNO3) بنسبة (60: 40٪) حيث قمنا باختبار هذا المزيج المنصهر باستخدام جهاز خاص يسمى (جهاز الماسح التفاضلي DSC) للتعرف على المواصفات الفيزيائية والكيميائية لمزيج أملاح النترات المنصهرة وقد تبين أنَّ درجة حرارة انصهار هذا المزيج الملحي هي (228.521 درجة مئوية) والحرارة الكامنة لتغير الطور من صُلب إلى سائل للمزيج الملحي المنصهر(114.321 كيلو جول / كغ)، وكانت النتائج متطابقة بالنسبة لدرجة الحرارة والحرارة الكامنة للمزيج الملحي المًنصهر وفقًا للعديد من المراجع العالمية. بالإضافة إلى أن نموذج الخزان الحراري يمتلك كفاءة طاقية حرارية تصل إلى نسبة (0.96) بينما الأنواع الأخرى من الخزانات الحرارية التي تعمل على (PCM) تصل إلى كفاءة الطاقة (0.66-0.70). بالتالي فإن الخزان الحراري المُصمم لديه طاقة كامنة عالية مناسبة لعمل المحطات الكهروشمسية الهجينة خلال فترات مختلفة من

   
  الكلمات  المفتاحية: التخزين الحراري ، الإشعاع الشمسي ، المحطات الهجينة ، مواد متغيرة الطور (PCM) ،  أملاح النترات ، الكفاءة الحرارية ، الحرارة الكامنة
   
  Introduction   
  The developed  system of the  heat storage prototype in the hydro solar gaseous plant  is  a thermal storage prototype contains materials with high thermal characteristics, which are  materials  with phase changing phase composed of salt mixture of  nitrate salts (sodium potassium nitrates) for obtaining the necessary energy source for heating the thermal transfer liquid  (thermal oil)  in  the solar field, this field is composed of several longitudinal rows and    parallel of concentrated solar panels which  concentrate the solar  radiation and heating this  liquid for helping  melting  these salts  and  generation of the  suitable thermal energy for operating the energy cycle and generating of solar steam and obtaining the electrical energy at  constant rate conform this station power, the operating  principle of the station depends of heating the thermal   transfer  liquid  which is thermal oil (thermonil) in the solar field system during solar radiation fall from  hour(0)  till hour (24)  during the day, and watching  the daily operating  behavior of the station in each working hour of the system. The station system is composed of two main parts which are: first part is the solar field prototype which is the source of thermal energy of the station, the second part is energy cycle module composed of  a number of heat exchangers for steam generation a number of heaters working on natural gas for station operating at low solar radiation called non-solar hours system  a special prototype of heat energy storage is developed in the hydro solar gaseous plant.  
  1 .RESEARCH SCOPE 
  The aim of this research  is to show the    experimental and  numerical results of the  designed  heat storage  prototype in electro-solar station, where the heat energy resulted from melting operation of  the used   mixer of nitrates in the prototype for obtaining and deterring a suitable  high level of  energy for operating the developed heat storage prototype in the  electro - solar  station   conform the   following steps: 
  1. Principle equations used in the designed heat storagee prototype for calculation of stored energy capacity. 
  2. Explication the working mechanism of heat storage prototype during starting of melting operation of nitrates salts mixture. 
  The developed thermal storage tank has thermal isolator of mineral wool on the geometric external body of the thermal tank designed for the surrounding ambient   with existence of a mixture of melted nitrates salts, this design conserves he heat energy from losing and infiltration at the work of this tank in electro - solar station.
  This prototype with cylindrical shape with following dimensions: volume 0.345( ) height 1(m),and external diameter 31(cm), it contains nitrates salts, salts mixture works in the determined temperature range from (260-550°C) .
    
  The experimental operation has three main aims at sacking of development of the developed heat storage which are: 
  1. Showing the working mechanism of this pattern for understanding the mechanism of thermal transfer during each single phase of charging and discharging of melted mixture of    nitrates salts.
  2. Showing the heat transfer mechanism during melting and solidification period of the mixture    inside the thermal tank.
  3. Showing and indication the experimental and designed statements of charging and discharging operations of the thermal tank model. The heat exchangers existing in the thermal tank contain a set of chrome pipes, the heat storage cylindrical body is made of stainless steel with diameter 31(cm) with     determined dimensions according to the volume
  change during charging phase, the thermal  hot oil  enters  from the  top and exit  from  the heat storage bottom,  returning to oil   reservoir  within a close  cycle, where the phase change material  (nitrates salts) is  melted, it will be a constant charging period of this material during melting operation. The main       problem in operating of  phase change materials (PCM)  is the low  heat conduction of (PCM),during the discharging of the heat storage the (PCM)   becomes  hard  on the   internal  surface of  pipes, the thermal  flux will    decrease as result of heat isolation  of the( PCM) thick layer , as there are two  layers: First  layer is the solid phase of   nitrates salts (sodium &potassium nitrates) as result of these salts           solidification  after    a period of time .
  Second layer: is the exterior pipe wall of heat exchangers pipes inside of the designed heat storage. It is important to calculated the  necessary  solidification time of the  mixture of  nitrates salts in the thermal tank pattern during solidification phase firstly,           secondly determination the thermal flow of solidification phase  at temperature difference between the internal surface touching the solidified material and the external surface of heat storage, the phase change of nitrates salts  depend on   temperature inside  heat storage  in relation with temperature of exterior   surface of  designed heat storage  prototype. The main reason  for selecting nitrates salts is that  they have  high latent energy comparing with other types of (PCM), they have high   temperature enabling them to work  in high thermal efficiency, as these salts work in the temperature rang  (260-550 ,and rate ( 4.6%) of volume increasing at the beginning of melting   operation of nitrates salts in the designed heat storage, consequently, selection of nitrates salts  as main material in  the designed  heat  storage  enable us to  obtaining a high rate of necessary heat energy for the operation of Rankine traditional energy cycle when using heat storage prototype at hybrid gaseous electro-solar station .
   The principle equation for energy calculation necessary for solidification and melting phase of (PCM) is determined by the following equation:   
 
   In addition to the   equation of phase change of (PCM) in form of latent energy which is: 
 
  Where: 
 

 

  2 .OPERATION WAY OF LATENT THERMAL TANK PATTERN
  The thermal storage tank is composed of the main following parts:
  1. Apot of stainless steel and type of (High Chrome 304).
  2 A pot designed for thermal oil.
  3. Apot with a cover designed for pressure conserving, which contains a mixture of melted nitrates salts in addition to electrical and mechanical valves. 
  4. A pump  special  for thermal oil transport  from oil tank  to thermal oil  pot  in addition to an electrical  coil and an external cover of stainless steel which has thickness of  0.8(mm), the  thermal tanks works as      follows:
  The thermal oil tank situated inside the internal pot of the developed    pattern is filled by an internal pump which bears high temperature at the starting of apparatus operation and raising of oil temperature.  The nitrates salts material is put inside the developed thermal tank. The nitrates salts is heated to constant temperature(221°C)and solidification temperature is( 238°C) for assuring disconnecting the bond of the   mixture entering the heat storage pattern,  consequently obtaining of the high complete latent heat at mixture   melting .
  The thermal oil is evacuated from the heat storage prototype to prevent any heat exchange between the material and the thermal oil at charging   ending.  
  The water of is  entered  around the  heat storage  body  from inside , then we  measure  the influence of  heat exchange between water and  melted  nitrates mixture, then we  draw the  change  curve on the  control screen according to different work conditions of hybrid electro-solar, gaseous station in case of high solar corresponding  the start of thermal oil heating to high    temperature by an electrical coil to a high temperature, then passing the heated thermal oil coming  from the concentrated solar  panels to thermal tank pattern to start the charging operation and   storing of thermal energy carried by the thermal oil and starting of  phase change by melting the salty mixture of  nitrates and to use this thermal  energy in water heating in the economizer, and  generating of steam, then roasting it, then leading it to a steam turbine for electricity generation, the figure(1) shows the designed thermal tank, the  figure(2) shows the digital control circuit (PLC:proportional linear controller) of the thermal tank, the figure(3) shows the    compared thermal tank which works on two separate materials and comparing the  graphic results  of the two pattern from the point of view of thermal efficiency conform the figures(4)and (5) and the figures(7) ,(8) and(9)
 

Figure 1. Thermal tank with control circuit (PLC)

 

Figure.2. Designed thermal tank

 

  3.EXPERIMENTAL RESULTS FOR THE LATENT THERMAL STORAGE TANK PROTOTYPE 
  Showing  the experimental results of heat storage prototype include display of   temperature change  of thermal oil, temperature of  PCM during  melting and solidification phases,entering and exit  temperatures of cooling  water to inside of heatstorage,this presentation is done conform the following main points: 
  1.   Showing the temperature changes curves of thermal oil inside the oil tank.
  2.  Showing the melting graphic of nitrates salts as main material with high latent    temperature, storing of heat energy is result of melting operation. 
  3. Realization of discharging of extra pressure inside thermal storage tank and determination   of the melting and the  solidification temperatures of  nitrates salt mixture inside the tank, and  determination the corresponding melting operation time of nitrates salts, We present the graphics  results extracted from the apparatus s at     starting of   operation  which show the changes of thermal indexes which regulate the operation of heat storage  during  the operations of charging and discharging ,these two operations are shown according to video file  designed according to      (LITE WAVE) program, where this video presents operations of charging and discharging of melted mixture of nitrates salts during two phases of melting and  solidification, the figure(1)  shows the designed heat storage prototype, and the figure(2) represents digital control  circuit(PLC:proportional digital linear      controller) of heat storage prototype, and the figure(3) represents the    compared heat storage. It is done three experiments, first one was preliminary each experiment has two stages, first stage represents charging  stage, heating of thermal oil, and nitrates salts mixture, the second stage is cooling stage  of designed tank  pattern at the end of melting operation, with the remark that all  experiments  were done at the same essential working conditions of the designed  thermal tank as from the quantity used in the experiment at the beginning of apparatus operation and temperature(350°C) ,and starting of phase change of  materials, the  graphic result were compared  with that of  other compared heat storage  which use phase change  materials with single salt  during  operating it in this  prototype  at the starting of operations of charge and  discharge for obtaining the  latent heat energy. An optional sample of salty mixture composed of Sodium &Potassium nitrates is tested by Differential Scanner Calorimetry produced by (SETARAM) company and the type (LABSYS) used for determination of  melting point of  the salty  mixture composed of (60%) Sodium nitrates and (40%) Potassium nitrates, the graphic   analysis  of  the results of   experimental  sample  test on this apparatus reveals  that  the melting point of salty mixture starts at (129.667°C) at certain conditions which are ten degrees for each one minute, an maximum heating range  till (250°C) in  nitrogen atmosphere.
  The testing sample for nitrates salts inside the thermal tank pattern is a sample composed of (60%) potassium nitrates and (40%) sodium nitrates  operated  on  the same  apparatus , the  graphic analysis results of this experimental  sample  of salty  mixture reveals that  the melting point of the salty mixture starts at the temperature (228.521°C )at certain conditions which are ten degrees for each one minute in nitrogen          atmosphere, the amount of latent  energy is       114.328  ( kj/kg)  as it is clear  in the  figure(6)  of the testing result of the sample, where it became clear the coincidence between the test results of nitrates salts sample  with tests   results of the sample of nitrate conform the designed program (framework dot net) during operating of  thermal tank  and melting of the full   quantity of  nitrates salts during   a period of (12) hours.                                                                              4. Determination of The offered quantity of thermal energy   presented by (PCM) represented in Sodium & Potassium nitrates salts mixture is   determined by the main equation (1) and equation (2) 
 

Figure 3. Thermal tank with control circuit (PLC)

 

Figure .4. Temperatures change in compared heat storage at using (Hydroquinone) as PCM 

 

Figure. 5. Temperatures change in the compared heat storage when using (d-mannitol) as (PCM)

 

Figure.6. test of a sample composed of sodium nitrates in percentage 60% and potassium nitrate 40% on (DSC) apparatus

  3.1   EXPERIMENTAL RESULTS OF LATENT THERMAL TANK PATTERN 
  1.  Results of first experiment: 
 

It is used a limited quantity of nitrates salts mixture (1.3) Kg, at apparatus operation we obtained identified results to that at doing operations of heating and cooling of   designed heat storage pattern.

 

  2. Results of the second experiment: 
  It is used a limited quantity of nitrates salts mixture (1.3) Kg, at apparatus operation identical results for thermal tank pattern.
   
  3. Results of the Third experiment:
  Discussion of the graphic results of the designed thermal tank pattern and comparing them with types of thermal tanks working on one phase (PCM). From the results shown previously, which are the first, second and third experiments of the thermal tank. The figures(7) till figure(9) shows the graphic  results of heat storage pattern design conform dimensions design   calculations of   heat storage , as it is shown  in these figures, the change of thermal oil  temperature  inside the oil tank    existed  in this  pattern design, where  all readings are  taken  from  the  design program called frame work dot net in interval of five   seconds from starting of  heat storage   tank  operating, according to the resulted  graphics , we found  that  the (PCM)  (mixture of Sodium &  Potassium nitrates)  temperature  change  as  explained in the curve (1) in the figure(8), and in the curve(1) in the   figure(7),the temperature is gradually increasing with operating time of heat storage tank (solid-solid: phase change), from the graphics in figure(8) it is clear that thermal oil temperature explained in curve(2)and in curve(2)in figure(9) begins to increase starting from operating on  moment reaching to the suitable design conditions of heat storage pattern limited by the melting temperature ( 221°C )and prevention, it is reaching to freezing temperature (238°C ), as  result it happened obviously  in the tank a thermal identified gradient increasing  descending graduation during heating period of   thermal oil at charging stage of this pattern ,the thermal oil curve(2) due to increases its slope in  figure(7),and increasing of salty   mixture  begins  to  increase and the melting phase  begins as explained in curve(1) in figure(7), then the mixture of salt will has a high latent  energy comparing with compared heat   storage  pattern. 
  As result of the comparison between heat storage pattern with another pattern in which  are used two single materials which are hydroquinone and               d-mannitol  as( PCM), we found  that these material, at the beginning of melting operation(solid-liquid change) have high latent heat  but not  as high as that of salty mixture used in operating  phase of heat storage tank      pattern, it  reveals also  that during the discharging phase of these used  materials  in these two  patterns, we found  that  the heat efficiency of salty mixture used in  heat storage pattern reaches the thermal efficiency factor of nitrates salts at discharging phase (0.965), and at charging(0.965) this means that the thermal efficiency of heat storage  tank  is  bigger than  that of the two previous  materials  when are used   separately  in the  compared heat storage pattern  at the  start of melting operation, the heat  efficiency factor for the   compared pattern at charging and  discharging are determined by the thermal properties values:  and   for the two (PCM ) used in the compared heat storage  pattern.                                             
  There are a numerical obvious approach and               coincidence between the experimental and computer of the designed heat storage tank  as explained in the figures(7) till (9),this coincidence appears in the temperature of salty mixture (nitrates salts) and thermal  oil as thermal transfer liquid as explained in the curve(1) and curve(2)  in the  figures (7) till (9)  in addition to the internal energy of the (PCM) during computer modeling period  with light change in thermal oil temperature at the beginning working of the designed heat storage conform the curve(2) as        explained in figure(8), then to keep a low pressure of the melted nitrates salts. Consequently there is             a numerical  approach and coincidence between the  experimental value measured at the test and the executed calculations at digital control circuit, by  comparing  the two  figures (4) and (5) which explain the graphic  results of the compared pattern of the  designed heat  storage, it  reveals to us that rate of heat  energy resulted by  melting of the two separate  materials is less than that in the designed heat storage pattern, also the accuracy  measurement of the designed heat storage is limited with the value(0.96) while for the compared tank is(0.26)  as explained in the two figures (4) & (5) ,the  thermal  energy offered by this pattern which uses mixture of  nitrates salts bigger than that in the compared pattern which uses two   single(PCM),consequently the identified thermal      variables represented in change in latent  energy and change in internal energy also the temperature of thermal transport liquid (thermal oil) in heat storage tank pattern will be higher and numerically  approaching to that in compared  thermal tank as from accuracy of measuring results as explained in the two figures(4) & (5), then  the best solution of the problem belonging to the (PCM) that have no high thermal  characteristics suitable for thermal storing, by using the melted nitrates salts and   remaining this  mixture for a long period  in the liquid state, keeping its physical and chemical  characteristics during  melting and solidification phases  in    the thermal tank pattern, and assuring obtaining  a high rate of latent heat energy during operation of  the designed  heat tank pattern  after ending of  heating and  melting operation of salty  mixture  and ending of cooling   operation as explained in the figures(7) till (9)  of the  graphic results of the designed thermal  tank pattern comparing with that  of the compared tank. 
  By comparing between the designed thermal tank pattern and the compared thermal tank explained in figure (3), we found the   followings: 
 

1.The designed heat storage tank pattern has  higher energy efficiency than  that  of the compared pattern  and has  bigger heat    energy  storing, the cause is the use of salty mixture  with high thermal characteristics not as  in the compared heat   storage tank  where was used  single material, this  made the  latent energy  rate bigger in the  thermal tank pattern at using less quantity of salty mixture than that used in the compared pattern where  are used two separate        materials  one at the  front of the  thermal tank and the another at its end. Way of (PCM)  location in the  thermal  storage tank participates in  decreasing of freezing time at the beginning of melting  operation, consequently  the designed  thermal storage tank has lesser  solidification time , this contributes in keeping the material  in its liquid phase  much more  than in compared thermal tank, this permits  repeating  the melting  mechanism  and mixture conservation which has thermal characteristics at melting process and decreasing solidification time and  preventing the melted mixture of reaching  to  solid crystal state, this is following by keeping the latent  thermal  energy, this is not  available in the compared  pattern of the  thermal tank which  uses two separate materials at melting  operation. 

 

  By  comparing  the energy efficiency  of the types of  thermal  storage tanks  existing  in the world, which work on (PCM) comparing with the designed heat storage tank, we found that  the energy efficiency of these types  varies  between (0.66)  and (0.70) , the energy  efficiency of the  designed  heat storage tank reaches (0.956),this means that the designed heat storage tank surpasses the compared pattern in percentage of (26%) according to  what it is explained  in   figures(4) and (5)consequently  there is   increase in the  thermal graduation and high energy level  in the   thermal  energy  offered by the  thermal oil, the  thermal energy  offered by the  nitrates salts mixture, as nitrates salts is distinguished by high rate of the  thermal  energy in spite of using them in limited low quantities comparing  with the compared pattern where  were used two single materials with big quantities in       addition to  the long  path of the melted mixture of these two materials according what it is  explained in the figures(4) & (5), as result the mixture of nitrates salts in its chemical composition possesses the characteristic of keeping the  physical   characteristics  at  liquid  phase and remaining in it for long period comparing with actual types of thermal storage        systems  which use  (PCM) but do not    possess high  energy level  and do not  realize the suitable thermal and physical characteristics for work conditions of   thermal storage systems, as the (PCM)  contain old bonds, so at the beginning of melting operation, the bindings bonds begin to disconnect, they need energy  that is   taken from completion of melting operation in the tank pattern, consequently, its organic structure  which contains  old  bonds that make  them keeping  their phase  change  when they are in   liquid or in solid state, completion of melting operation and quickly approaching to solid crystalline state comparing with the melted nitrates salts which realizes  that the reality of the physical and  chemical characteristics  as   a  mixture  used in  the developed thermal tank pattern, then  the melting  operation needs  less energy for  disconnecting  the melted mixture bonds, and keeping it in the  liquid state for longer  period  comparing with rest (PCM) which  differ in their organic characteristics and composition, this decreases the thermal energy during  melting   operation, it will be loss  in latent    energy, this gives us the ideal possibility for  linking the thermal  storage tank pattern with electro-solar station system and  obtaining the electrical energy. The thermal oil can keep the main operation conditions represented in melting the salty mixture at determined design conditions, a remaining the salty mixture in liquid state and preventing it from reaching to crystalline solid state. Consequently. We found in the curves that this mixture remains keeping the melting sill without reaching to crystalline solid state Consequently, the increase of latent energy a   result of melting operation at thermal oil   temperature, these curves explain that the thermal oil keep  the temperature (250°C) suitable for keeping the salty mixture in liquid state an operating conditions Determined by the melting temperature(228°C) and certain freezing temperature (238°C) [12][13][14] .      
 
  Figure. 7.  Results of the first stage of heating and cooling of (PCM) and the thermal oil inside the thermal tank   pattern designed for the first experiment
       
  Figure 8. Results of the first stage of heating and cooling of (PCM) and the thermal oil inside the thermal tank pattern designed for the second experiment.
 
  Figure 9.  Results of the first stage of heating and cooling of (PCM) and the thermal oil inside the thermal tank pattern designed for the first experiment.
   
   
   
  4 .CONCLUSIONS 
  1. Realization of a design for thermal storage tank pattern which is different of different types of thermal storage tanks.
  2.This designed thermal storage tank pattern is characteristic with existence of thermal isolator called metallic wool, and using of  suitable quantities of nitrate salts mixture which gives bigger thermal efficiency with keeping the resulted thermal energy by melting and preventing the solidification of  nitrates  salts  inside the  thermal tank pattern. 
  3. Through  the figures  from (3) to (6) and as result of comparison between the  designed  heat storage  tank  with the   compared one, we found that  the change rate energy efficiency of  designed  thermal  tank pattern and the compared thermal tank  pattern at using  mixture for nitrate salts is:   
  From the equation it results that the designed heat storage tank surpasses the compared pattern as from measuring  accuracy which reaches(0.96) while for the compared  pattern it takes the value (0.26), the thermal energy offered by designed pattern comparing with that of the compared pattern is bigger, mentioning that  in the  designed heat storage tank it is used mixture of  nitrates salts  while in the compared   pattern it is used  two separate (PCM)during determined time of charging and discharging during operation of  melting and solidification.
  4.The developed tank pattern solves a major problem in thermal storage systems that do not contain the same high thermal properties of materials, and this problem concerns the period of thermal energy storage for long-term periods of time without change in the thermal characteristics through the conservation of thermal energy and prevent them from being lost as     a result of  containment of this  model to the mix of salts of melted nitrates salts ,which achieve thermal storage properties due to chemical installation to the mix and  remaining in this liquid state for a long time in this case by reducing the melting time of the used     mixture, this is experimentally proved at testing of the latent thermal tank pattern  in comparison with the rest of the phase change materials used in thermal  storage which possess this property when working during phases fusion and  solidification.
  5.It was determined the melting point of  a mixture of Sodium nitrate and Potassium nitrate which is (228.521°C) and latent heat associated with the process of the phase change from solid to liquid  (114.328 kj/kg ). 
   
 
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